Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method
Abstract & Details
Research Area
Chemical Kinetic
Keywords
Keywords: Kinetics
Oxidation
L- Histidine
Cerium (IV)
Pd(II)
Sulphuric acid
KCl
Mechanism.
Abstract
Abstract
The rate of reaction of L-histidne with Ce (IV) acidic medium has been kinetically studied in the presence of Pd (II) as catalyst using a spectrometric method. The reactions have been performed at temperatures range from 298 K to 318 K in interval of 10 minutes. In the case of Ce (IV), this reaction would be a first order reaction. The results exhibits first order each in Ce (IV) and metal ion Pd(II) and positive fractional order with respect to [L-Histidine]. This would have a first order reaction between the Ce (IV) and L- histidine in the presence and absence SDS, CTAB and KCl. The rate constant decreases with increasing the concentration of [HSO4-] and [H+] ion. The thermodynamical parameter values such as ∆H#, ∆G# and ∆S# are increases with increaseing temperature.
kobs = (kK[L-pro][Pd(II)])/(1+K[H^+ ][L-pro])
License
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Commons
Attribution-ShareAlike 4.0 International License.
Author Information
| # | Name | Institute / Affiliation |
|---|---|---|
| 1 | Gajanand Sahu | Govt. Nagarjuna P.G. College of Science, Raipur (C.G.) |
| 2 | Sanjay Ghosh | Govt. Nagarjuna P.G. College of Science, Raipur (C.G.) |
| 3 | Deepak Sinha | Govt. Nagarjuna P.G. College of Science, Raipur (C.G.) |
| 4 | Vinod Kumar Jena | Govt. Nagarjuna P.G. College of Science, Raipur (C.G.) |
| 5 | P.C.Sharma | Govt. Nagarjuna P.G. College of Science, Raipur (C.G.) |
How to Cite
Use the following formats to cite this article in your research.
APA Style
Sahu, Gajanand, Ghosh, Sanjay, Sinha, Deepak, Jena, Vinod Kumar, & P.C.Sharma (2024). Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method. International Journal of Advance Research and Innovative Ideas In Education, 10(2), 1863-1876.
MLA Style
Sahu, Gajanand, et al. "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method." International Journal of Advance Research and Innovative Ideas In Education, vol. 10, no. 2, 2024, pp. 1863-1876.
IEEE Style
Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena, and P.C.Sharma, "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method," International Journal of Advance Research and Innovative Ideas In Education, vol. 10, no. 2, pp. 1863-1876, 2024.
Vancouver Style
Sahu Gajanand, Ghosh Sanjay, Sinha Deepak, Jena Vinod Kumar, P.C.Sharma. Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method. International Journal of Advance Research and Innovative Ideas In Education. 2024;10(2):1863-1876.
Harvard Style
Sahu, Gajanand, Ghosh, Sanjay, Sinha, Deepak, Jena, Vinod Kumar, & P.C.Sharma (2024) 'Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method', International Journal of Advance Research and Innovative Ideas In Education, 10(2), pp. 1863-1876.
Chicago Style
Sahu, Gajanand, et al. "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method." International Journal of Advance Research and Innovative Ideas In Education 10, no. 2 (2024): 1863-1876.
Turabian Style
Sahu, Gajanand, et al. "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method." International Journal of Advance Research and Innovative Ideas In Education 10, no. 2 (2024): 1863-1876.
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